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氨法脱碳过程中氨逃逸规律及其抑制

马双忱 陈公达 温佳琪 马岚 焦坤灵

化工学报2016,Vol.5Issue(5):2064-2069,6.
化工学报2016,Vol.5Issue(5):2064-2069,6.DOI:10.11949/j.issn.0438-1157.20151437

氨法脱碳过程中氨逃逸规律及其抑制

Ammonia escape and its prevention in CO2 absorption process using ammonia solution

马双忱 1陈公达 1温佳琪 1马岚 1焦坤灵1

作者信息

  • 1. 华北电力大学环境学院,河北保定 071003
  • 折叠

摘要

Abstract

With awareness of environmental protection in recent years, control of greenhouse gas emission has become an important issue. A large port of CO2 come from power plants combustion of fossil fuel, and its capture is necessary for fire-coal power plants. Chemical absorption of CO2 by alkaline absorbent is one of widely use methods. Among the removal technologies of air pollutants by chemical absorbents, ammonia method has many advantages. However, ammonia method has a serious ammonia escape problem, leading to a less favorable selection for the application. The effects of CO2 concentration, ammonia concentration, absorption temperature on ammonia escape were experimentally investigated in the paper. Based on consideration of coordination chemistry principle, some metal ions were selected and studied as additives. The results indicated that addition of Ni2+ showed a good performance for the control of ammonia escape, and it was confirmed by the results obtained by UV-visible spectrophotometer. These results could be valuable for solution of ammonia escape.

关键词

碳捕集/氨水/氨逃逸/吸收/化学过程

Key words

carbon capture/ammonia solution/ammonia escape/absorption/chemical processes

分类

资源环境

引用本文复制引用

马双忱,陈公达,温佳琪,马岚,焦坤灵..氨法脱碳过程中氨逃逸规律及其抑制[J].化工学报,2016,5(5):2064-2069,6.

基金项目

中央高校基本科研业务费专项资金( 2014ZD39 , 2014XS84).supported by the Fundamental Research Funds for the Central Universities (2014ZD39, 2014XS84). ( 2014ZD39 , 2014XS84)

化工学报

OA北大核心CSCDCSTPCD

0438-1157

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