石油化工2016，Vol.45Issue(5)：570-575,6.DOI:10.3969/j.issn.1000-8144.2016.05.010
长链烷基改性苯基含氢硅油的制备与表征
Synthesis and characterization of long-chain alkyl modified phenyl hydrogen-containing silicone oil
摘要
Abstract
Phenyl hydrogen-containing silicone oil with long-chain alkyl was prepared through the hydrosilylation reaction of 1-dodecene and phenyl hydrogen-containing silicone oil with isopropanol as the solvent and chloroplatinic acid as the catalyst. The structure of the product was verified by means of FTIR and1H NMR. The effects of temperature,reaction time,catalyst dosage,molar ratio of Si—H to CC and dropping way of 1-dodecene on the conversion of Si—H were investigated. The reaction conditions were optimized through orthogonal experiments. The results showed that,under the optimized conditions of reaction time 5.0 h,temperature 115℃,catalyst dosage 30μg/g,n(Si—H)∶n(CC)=1∶1.10 and dropping time of 1-dodecene 25 min,the conversion of Si—H reached 82.25%.关键词
硅氢反应/苯基含氢硅油/长链烷基Key words
hydrosilylation/phenyl hydrogen-containing silicone oil/long-chain alkyl分类
化学化工引用本文复制引用
郭睿,杨江月,祁文杰..长链烷基改性苯基含氢硅油的制备与表征[J].石油化工,2016,45(5):570-575,6.基金项目
陕西省科学技术研究发展计划项目（2013K11-19）；陕西省科技统筹创新工程计划项目（2014KTCL01-11）。 （）
