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氧化石墨烯-铁酸镍杂化催化剂可见光降解氨氮

周姗姗 肖波 刘成宝 刘守清

苏州科技学院学报(自然科学版)2016,Vol.33Issue(2):23-29,7.
苏州科技学院学报(自然科学版)2016,Vol.33Issue(2):23-29,7.

氧化石墨烯-铁酸镍杂化催化剂可见光降解氨氮

Photocatalytic degradation of ammonia via graphene oxide-nickel ferrite hybrid catalyst under visible light irradiation

周姗姗 1肖波 2刘成宝 1刘守清2

作者信息

  • 1. 江苏省环境功能材料重点实验室,江苏 苏州215009
  • 2. 苏州科技大学 化学生物与材料工程学院,江苏 苏州215009
  • 折叠

摘要

Abstract

Nickel ferrite was modified with graphene oxide (GO), in which graphene oxide-nickel ferrite (GO-NiFe 2O4) hybrid catalyst was yielded. GO activated the photocatalytic activity of nickel ferrite to hydrogen peroxide, which resulted in the photo-Fenton degradation of ammonia in alkaline solution using the hybrid photocatalyst under visible light irradia-tion. The effects of pH, GO content, H2O2 concentration on the degradation ratio were explored. The results show that A GO-NiFe2O4 catalyst with the mass concentration of 4.0% GO in NiFe2O4 produces an optimal degradation ratio of 90.5%at 8 h for the ammonia abatement in pH 10.5 solution with 1.0 mmol·L-1 H2O2 under visible light irradiation. The stability tests show that the degradation ratio is almost constant for eight runs, which indicates the GO-NiFe 2O4 catalyst is very sta-ble. The material can be used to deal with wastewater polluted with ammonia.

关键词

铁酸镍/氧化石墨烯/光芬顿//降解

Key words

nickel ferrite/graphene oxide/photo-fenton/ammonia/degradation CLC number:X506

分类

资源环境

引用本文复制引用

周姗姗,肖波,刘成宝,刘守清..氧化石墨烯-铁酸镍杂化催化剂可见光降解氨氮[J].苏州科技学院学报(自然科学版),2016,33(2):23-29,7.

基金项目

国家自然科学基金资助项目(21347006);江苏省自然科学基金资助项目(BK20141178);绿色催化四川省高校重点实验室开放项目(LZJ1304);苏州市科技局纳米专项 ()

苏州科技学院学报(自然科学版)

2096-3289

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