井冈山大学学报（自然科学版）Issue(4)：28-32,5.DOI:10.3969/j.issn.1674-8085.2013.04.006
电荷转移配合物[N-（4-氟-苄基）-3,5-二甲基吡啶][Ni（dmit）2]的合成及其晶体结构
SYNTHESIS AND CRYSTAL STRUCTURE OF THE CHARGE TRANSFER COMPLEX [N-(4-FLUOROBENZYL)-3,5-DIMETHYLPYRIDINIUM] [Ni(DMIT)2]
摘要
Abstract
A new charge transfer complex, [N-(4-fluorobenzyl)-3,5-dimethylpyridinium] [Ni(dmit)2] (1), in which dmit is same as 4,5-dimercapto-1,3-dithiole-2-thione, has been prepared and characterized by elemental analysis, IR and single-crystal X-ray diffraction. 1 crystallizes in the space group P21/c of the monoclinic system with eight formula units in a cell: a = 8.1372(9), b = 27.549(3), c = 11.7528(13) ?, β = 93.163(2)°, V = 2630.6(5) ?3, C20H15FNNiS10, Mr = 667.64, Dc = 1.686 g/cm3, S = 1.003, Z = 4, F(000) = 1356, R1 = 0.0352 and wR2=0.0.1036. The anions of [Ni(dmit)2]-stacks into dimers, which further construct into a 2-D framework structure through lateral S…S interactions.关键词
1,3-二硫醚-2-硫酮-4,5-二硫烯/电荷转移配合物/合成/晶体结构/表征Key words
2-thioxo-1,3-dithiole-4,5-dithiolene/charge transfer complex/synthesis/crystal structure/symptom分类
数理科学引用本文复制引用
黄良芳,张辉..电荷转移配合物[N-（4-氟-苄基）-3,5-二甲基吡啶][Ni（dmit）2]的合成及其晶体结构[J].井冈山大学学报（自然科学版）,2013,(4):28-32,5.基金项目
安徽省高校自然科学基金研究项目(KJ2012B178 （）
KJ2012ZD11) （）
黄山学院科研项目(2012xkjq010 （）
2012xkjq012) （）
