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离子交换法提取大量钍中微量铀

陈姆妹 李峥 何淑华 张岚

核化学与放射化学2016,Vol.38Issue(3):159-165,7.
核化学与放射化学2016,Vol.38Issue(3):159-165,7.DOI:10.7538/hhx.2016.38.03.0159

离子交换法提取大量钍中微量铀

Recovery of Trace Uranium From Large Quantities of Thorium

陈姆妹 1李峥 1何淑华 1张岚1

作者信息

  • 1. 中国科学院 上海应用物理研究所,中国科学院 核辐射与核能技术重点实验室,上海 201800
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摘要

Abstract

This work describes the ion exchange separation of trace amounts of uranium from large quantities of thorium and fission product elements .The fission elements were investi‐gated including Cs ,Sr ,Y ,Zr ,Nb ,Ru ,Rh ,La ,Ce and Eu .The separation method employed Dowex1 × 8 as anion exchanger and Dowex50 × 8 as cation exchanger . U was strongly adsorbed on the Dowex1 × 8 resin from a medium of 8 mol/L HCl .Then washed the column by 8 mol/L HCl‐0.2 mol/L NH4 F mixture .The large quantities of Th as well as other elements concerned passed into the effluent and were thus separated .U was eluted using 0.05 mol/L HNO3 .The U product contaminated pud with even equal concentration of Th can be satisfactorily purified by feeding directly to the cation exchange column and stripping using 2 mol/L HNO3 to achieve the final purification of U from Th .

关键词

离子交换///裂片元素

Key words

ion exchange/thorium/uranium/fission element

分类

能源科技

引用本文复制引用

陈姆妹,李峥,何淑华,张岚..离子交换法提取大量钍中微量铀[J].核化学与放射化学,2016,38(3):159-165,7.

基金项目

中国科学院战略性科技先导专项---钍基熔盐堆核能系统 ()

核化学与放射化学

OA北大核心CSCDCSTPCD

0253-9950

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