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含3,5-二硝氨基-1,2,4-三唑肼盐推进剂的能量特性计算

周诚 毕福强 王伯周 李祥志 李吉祯 周群

火炸药学报2016,Vol.39Issue(3):80-83,88,5.
火炸药学报2016,Vol.39Issue(3):80-83,88,5.DOI:10.14077/j.issn.1007-7812.2016.03.016

含3,5-二硝氨基-1,2,4-三唑肼盐推进剂的能量特性计算

Energetic Characteristics Computation of Propellants Containing Hydrazinium 3,5-Diamino-1,2,4-triazole

周诚 1毕福强 1王伯周 1李祥志 2李吉祯 1周群1

作者信息

  • 1. 西安近代化学研究所,陕西西安710065
  • 2. 氟氮化工资源高效开发与利用国家重点实验室,陕西西安710065
  • 折叠

摘要

Abstract

To evaluate the application prospect of novel nitrogen‐rich compound hydrazinium 3 ,5‐diamino‐1 ,2 ,4‐triazole (HDNAT ) as composite solid propellant components ,the energy characteristics of hydroxy terminated polybutadiene (HT‐PB) propellant ,glycidyl azide polymer (GAP) propellant and composite modified double‐base(CMDB) propellant containing HDNAT were calculated by NASA‐CEA software under the standard condition (pc ∶ p0 =70∶1) .The iso‐property trigo‐nal figures of standard theory specific impulse Isp ,characteristic velocity C* ,combustion temperature Tc and average rela‐tive molecular weight of combustion gas Mw for HTPB/Al/AP/HDNAT propellant(the largest mass fraction of Al is 20% ) were drawn out .The results show that the Isp of HDNAT monopropellant is 2533 .0 N · s/kg .When the mass fraction of HDNAT in HTPB propellant is 50% ,the largest Isp is 2658 .0 N · s/kg ,improves by 326 .6 N · s/kg compared with the basic formulation .When the mass fraction of HDNAT in GAP propellant is 30% ,the largest Isp is 2529 .0 N · s/kg ,im‐proves by 252 .7 N · s/kg compared with the basic formulation .When the mass fraction of HDNAT in CMDB propellant is 27% ,the largest Isp is 2593 .1N · s/kg ,improves by 57 .3N · s/kg compared with the basic formulation .

关键词

物理化学/固体推进剂/3, 5-二硝氨基-1, 2, 4-三唑肼盐/HDNAT/能量特性/NASA-CEA软件

Key words

physical chemistry/solid propellant/hydrazinium 3 ,5-diamino-1 ,2 ,4-triazole/HDNAT/energy charac-teristics/NASA-CEA software

分类

军事科技

引用本文复制引用

周诚,毕福强,王伯周,李祥志,李吉祯,周群..含3,5-二硝氨基-1,2,4-三唑肼盐推进剂的能量特性计算[J].火炸药学报,2016,39(3):80-83,88,5.

基金项目

总装基础科研基金 ()

火炸药学报

OA北大核心CSCDCSTPCD

1007-7812

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