火炸药学报2016，Vol.39Issue(3)：106-106,1.DOI:10.14077/j.issn.1007-7812.2016.03.021
动力学机理函数的导出途径、逻辑选择／确定及在含能材料分解反应速率方程中的一些应用
Derived Ways and Logical Choice/Determination of the Mechanism Functions and Their Some Application in Rate Equation of the Decomposition Reaction of Energetic Materials
摘要
Abstract
The common kinetic mechanism functions were derived ,which include the diffusion mechanism function , the random nucleation and the subsequent growth mechanism function ,the power law mechanism function ,the phase boundary reaction mechanism function and the chemical reaction mechanism function .The technical approach for logical selection and determination of the most probable mechanism function was presented .The function mecha‐nisms of decomposition reaction of some energetic materials were collected and expatiated .The mechanism function and rate equation of the exothermic decomposition reaction process of 6b‐nitrohexahydro‐2H‐1 ,3 ,5‐trioxacyclopenta [cd]‐pentalene‐2 ,4 ,6‐triyl trinitrate (NHTPN) are reported with 79 references .关键词
物理化学/分解反应/机理函数/动力学参数/NHTPNKey words
physical chemistry/decomposition reaction/mechanism function/kinetic parameters/NHTPN分类
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胡荣祖,罗阳,赵宏安,姚二岗,马海霞,张教强,张海,高红旭,曲文刚,仪建华,赵凤起..动力学机理函数的导出途径、逻辑选择／确定及在含能材料分解反应速率方程中的一些应用[J].火炸药学报,2016,39(3):106-106,1.基金项目
国家自然科学基金 （）
