安徽农业科学2016,Vol.44Issue(16):7-8,13,3.
大气污染物中2-甲基丁四醇硫酸酯的质谱解析
Mass Spectrometry of 2-Methyltetrol-oganosulfates in Atmospheric Pollutant
摘要
Abstract
The liquid chromatography/ negative ion electrospray ionization mass spectrometry (LC/ ( - )ESI - MS) was used to analyze an aerosol sample collected from Dongping National Forest Park in Chongming influenced by anthropogenic activities. Diastereoisomeric organosulfates formed from the chemical reaction of SO2 and 2 - methyltetrols which are the major markers of isoprene secondary organic aerosol were found and separated. Taking the previous information into account,erythro - and threo - 2 - methyltetrol organosulfates were characterized based on mass spectral fragmentation.关键词
有机硫酸酯/2-甲基丁四醇/液相色谱/负离子电喷雾质谱( LC/(-) ESI-MS)Key words
Organo-sulfate/2-methyltetrols/Liquid chromatography/negative ion electrospray ionization mass spectrometry(LC/(-)ESI-MS)分类
资源环境引用本文复制引用
杨颜,汪午..大气污染物中2-甲基丁四醇硫酸酯的质谱解析[J].安徽农业科学,2016,44(16):7-8,13,3.基金项目
国家自然科学基金项目(21377078)。 (21377078)