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大气污染物中2-甲基丁四醇硫酸酯的质谱解析

杨颜 汪午

安徽农业科学2016,Vol.44Issue(16):7-8,13,3.
安徽农业科学2016,Vol.44Issue(16):7-8,13,3.

大气污染物中2-甲基丁四醇硫酸酯的质谱解析

Mass Spectrometry of 2-Methyltetrol-oganosulfates in Atmospheric Pollutant

杨颜 1汪午2

作者信息

  • 1. 安徽省巢湖市环境保护监测站,安徽巢湖238000
  • 2. 上海大学环境污染与健康研究所,上海200444
  • 折叠

摘要

Abstract

The liquid chromatography/ negative ion electrospray ionization mass spectrometry (LC/ ( - )ESI - MS) was used to analyze an aerosol sample collected from Dongping National Forest Park in Chongming influenced by anthropogenic activities. Diastereoisomeric organosulfates formed from the chemical reaction of SO2 and 2 - methyltetrols which are the major markers of isoprene secondary organic aerosol were found and separated. Taking the previous information into account,erythro - and threo - 2 - methyltetrol organosulfates were characterized based on mass spectral fragmentation.

关键词

有机硫酸酯/2-甲基丁四醇/液相色谱/负离子电喷雾质谱( LC/(-) ESI-MS)

Key words

Organo-sulfate/2-methyltetrols/Liquid chromatography/negative ion electrospray ionization mass spectrometry(LC/(-)ESI-MS)

分类

资源环境

引用本文复制引用

杨颜,汪午..大气污染物中2-甲基丁四醇硫酸酯的质谱解析[J].安徽农业科学,2016,44(16):7-8,13,3.

基金项目

国家自然科学基金项目(21377078)。 (21377078)

安徽农业科学

0517-6611

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