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锌铝池中Si含量对渣相形成的影响

涂浩 潘修河 吴长军 苏旭平 刘亚 王建华

工程科学学报2016,Vol.38Issue(7):945-951,7.
工程科学学报2016,Vol.38Issue(7):945-951,7.DOI:10.13374/j.issn2095-9389.2016.07.008

锌铝池中Si含量对渣相形成的影响

Effect of Si content in the zinc-aluminium bath on the formation of slag phase

涂浩 1潘修河 2吴长军 1苏旭平 2刘亚 1王建华2

作者信息

  • 1. 常州大学材料表面科学与技术重点实验室,常州213164
  • 2. 常州大学光伏科学与工程协同创新中心,常州213164
  • 折叠

摘要

Abstract

The solubility of silicon in a Zn-50%Al- xFe- ySi ( in atomic fraction) molten bath and the content of silicon in a Zn-30%Al-2%Fe-xSi ( in mass fraction) molten bath corresponding to the appearing of τ5 slag phase and the disappearing of FeAl3 phase were calculated at different temperatures using the Thermo-Calc software. At the same time, the solubility of silicon in liquid phase in the Zn-50%Al-xFe-ySi alloy and the phase equilibrium relationship of the Zn-30%Al-2%Fe-xSi alloy were experimentally determined by using the equilibrium alloy method. The results show that the calculated solubility of silicon in liquid phase in the Zn-50%Al-xFe-ySi system at 540, 560, 580, 600 and 620℃ are 0. 82%, 0. 95%, 1. 11%, 1. 28% and 1. 47%, respectively, which agree well with the experimental data. When the temperature of the molten bath is 580, 600, and 620℃, the calculated content of silicon in the Zn-30%Al-2%Fe- xSi alloy corresponding to the appearing of τ5 phase in the molten bath is 0. 6%, 0. 72% and 0. 84%, and the values corresponding to the disappearing of FeAl3 phase are 1. 12%, 1. 22% and 1. 34%, respectively, which agree basically with the experimental results.

关键词

热浸镀锌/硅含量/热力学计算/

Key words

hot dip galvanizing/silicon content/thermodynamic calculations/slag

分类

矿业与冶金

引用本文复制引用

涂浩,潘修河,吴长军,苏旭平,刘亚,王建华..锌铝池中Si含量对渣相形成的影响[J].工程科学学报,2016,38(7):945-951,7.

基金项目

国家自然科学基金资助项目(51271041 ()

51271040) ()

江苏高校优势学科建设工程资助项目 ()

工程科学学报

OA北大核心CSCDCSTPCD

2095-9389

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