高压物理学报2016，Vol.30Issue(4)：265-270,6.DOI:10.11858/gywlxb.2016.04.001
三元铁基金属氮化物的高压复分解反应合成
High-Pressure Solid-State Metathesis Synthesis of Ternary Iron-Based Metal Nitrides
摘要
Abstract
Ternaryε-Fe3-x MxN1+δ(M=Co,Ni)were synthesized as spherical bulk materials with variable components through composite high-pressure solid-state metathesis (HPSSM)reactions under 5 GPa and at 1 673 K,employing diversity binary metal oxides (Fe2 O3 ,CoO,NiO)and hBN as the reaction precursors.The structural characterizations of the as-prepared iron-based metal nitrides were determined by X-ray powder dif-fraction (XPD),field-emission scanning electronic microscopy (FE-SEM)and high-resolution transmission electron microscope (HRTEM),etc.First-principles calculations were used to explore the effect of pressure on the reaction enthalpyΔH in HPSSM.Our results show that the high-pressure confinement environment is favorable for the synthesis of high-quality metal nitrides,and the HPSSM reaction is an effective synthetic route to the bulk iron-based metal nitrides.关键词
铁基金属氮化物/高压固相复分解反应/反应焓Key words
iron-based metal nitride/high-pressure solid-state metathesis reaction (HPSSM)/reaction enthalpy分类
数理科学引用本文复制引用
高上攀,曾雉,彭放,贺端威,入舩徹男,雷力,胡启威,房雷鸣,王贤龙,大藤弘明,小岛洋平,张雷雷,谭立洁..三元铁基金属氮化物的高压复分解反应合成[J].高压物理学报,2016,30(4):265-270,6.基金项目
国家自然科学基金（21301122）；高等学校博士学科点专项科研基金 （）
