化工进展2016，Vol.35Issue(7)：2046-2056,11.DOI:10.16085/j.issn.1000-6613.2016.07.016
低碳烯烃齐聚合成液体燃料研究进展
Progress on the catalytic oligomerization of light olefins to liquid fuel
摘要
Abstract
Catalytic oligomerization reaction,by employing light olefins as raw materials,paves an important route for producing clean liquid fuels. Currently,in the industrialization of olefin oligomerization,the development of heterogeneous catalysts with high-activity,favorable stability and well concentrated product distribution is an emerging direction. In this review,the catalytic reaction mechanisms of olefin oligomerization on both the acid and nickel active centers of heterogenous catalysts were summarized. We mainly introduced the oligomerization reactions with C2=,C3= and their mixtures. Accordingly,the optimal designing of heterogeneous catalysts,including the type of supports,pore structures and the distribution of active centers,as well as the optimization of reaction conditions of oligomerization reactions were reviewed. Moreover,the advantages and disadvantages of producing liquid fuels from heterogenous catalysis of light olefins were prospected,which provides a theoretical guidance for the development of promising industrial catalysts with high selectivity and long-life.关键词
低碳烯烃/齐聚反应/清洁液体燃料/分子筛/催化剂Key words
light olefin/oligomerization/clean liquid fuel/molecular sieve/catalyst分类
化学工程引用本文复制引用
苏雄,段洪敏,黄延强,王晓东,张涛..低碳烯烃齐聚合成液体燃料研究进展[J].化工进展,2016,35(7):2046-2056,11.基金项目
国家自然科学基金（21206159，21476226，21506204）及大连化学物理研究所洁净能源基础研究专项基金（DICP M201307）项目。 （）
