化工进展2016,Vol.35Issue(7):2063-2070,8.DOI:10.16085/j.issn.1000-6613.2016.07.018
石墨相氮化碳光催化剂研究进展
Research progress of graphitic carbon nitride in photocatalysis
郭雅容 1陈志鸿 1刘琼 1张正国 1方晓明1
作者信息
- 1. 华南理工大学化学与化工学院传热强化与过程节能教育部重点实验室,广东广州 510640
- 折叠
摘要
Abstract
As a visible light responding polymer and semiconductor photocatalyst,graphitic carbon nitride(g-C3N4)has the advantages of cheap and readily available,chemically stable,non-toxic and harmless,as well as having suitable band gap and band positionetc. However,g-C3N4 can only absorb light shorter than 460nm and its photogenerated carriers recombine severely,which has restricted its application. Modification of g-C3N4 is an effective means to improve its photocatalytic ability. This article outlines the structure,properties and preparation methods of g-C3N4,then focuses on the research progress of g-C3N4,including morphology controlling,compounding with semiconductors,element doping,molecular doping and dye-sensitized. It also discusses the applications of g-C3N4 in pollutants removal,hydrogen evolution,CO2 reduction and other aspects of organic synthesis. The prospects for the development of g-C3N4 based photocatalysts are also discussed,and the research direction of graphitic carbon nitride are proposed as multiple modification,application and mechanism exploration.关键词
石墨相氮化碳/催化剂/太阳能/制氢/聚合物Key words
graphitic carbon nitride/catalyst/solar energy/hydrogen production/polymers分类
化学引用本文复制引用
郭雅容,陈志鸿,刘琼,张正国,方晓明..石墨相氮化碳光催化剂研究进展[J].化工进展,2016,35(7):2063-2070,8.