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山核桃壳活性炭对煤气洗涤水的吸附净化

李郑鑫 谌伦建 叶云娜 徐冰 刘凯 刘建伟 张乐 苏毓

化工进展2016,Vol.35Issue(7):2236-2241,2242,7.
化工进展2016,Vol.35Issue(7):2236-2241,2242,7.DOI:10.16085/j.issn.1000-6613.2016.07.041

山核桃壳活性炭对煤气洗涤水的吸附净化

Purification of gas washing water from underground coal gasification by activated carbon prepared from pecan shell

李郑鑫 1谌伦建 1叶云娜 1徐冰 1刘凯 1刘建伟 1张乐 1苏毓1

作者信息

  • 1. 河南理工大学材料科学与工程学院,河南焦作 454000
  • 折叠

摘要

Abstract

Activated carbon with pecan shell as raw material,after phosphate impregnation, carbonization and activation,can be produced. The surface morphology and pore size distribution of the activated carbons were characterized by SEM and nitrogen adsorption measurement.Furthermore, gas washing water from model test of underground coal gasification was purified by pecan shell activated carbon. The removal effects of volatile phenol,TOC、COD、ammonia and some elements were investigated. Results showed that the specific surface area and total pore volume of prepared activated carbon can be 2959m2/g and 2.223cm3/g. It incorporate both micro-pore and meso-pore with pore size range of 1—6nm. The removal rates of volatile phenol,TOC and COD values by pecan shell activated carbon after 45h can be 99.75%,88.33% and 65.73%,respectively. The removal rates of ammonia and trace elements after adsorption for 15 h reaches 80.71% and higher than 99%.

关键词

活性炭/吸附/吸附剂/制备/修复

Key words

activated carbon/adsorption/adsorbents/preparation/remediation

分类

化学工程

引用本文复制引用

李郑鑫,谌伦建,叶云娜,徐冰,刘凯,刘建伟,张乐,苏毓..山核桃壳活性炭对煤气洗涤水的吸附净化[J].化工进展,2016,35(7):2236-2241,2242,7.

基金项目

国家自然科学基金(51174077,51404098)及教育部博士点基金(20124116110002)项目。 ()

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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