燃料化学学报2016，Vol.44Issue(7)：801-814,14.
合成气催化转化直接制备低碳烯烃研究进展
Research progress in the direct conversion of syngas to lower olefins
摘要
Abstract
The direct conversion of syngas to lower olefins is one of the most challenging subjects in the field of C1 chemistry; it is considered as a new attractive route for producing lower olefins from non-petroleum resources, owing to its process simplicity and low energy consumption. Bifunctional catalysis using composite catalysts such as OX-ZEO and Fischer-Tropsch to olefins ( FTO) reaction are two main pathways for the direct conversion of syngas to lower olefins. In this paper, the recent research progress made in the direct conversion of syngas to lower olefins via these ways was reviewed. The catalysis mechanism for olefins formation, the design and development of novel catalysts, as well as the effect of various additives on the catalyst performance were considered;lastly, an expectation outlook was given on the future trend for the direct conversion of syngas to lower olefins.关键词
低碳烯烃/合成气/费托反应/双功能催化/反应机理/纳米催化Key words
lower olefins/syngas/Fischer-Tropsch reaction/bifunctional catalysis/reaction mechanism/nanometer catalysis分类
生物学引用本文复制引用
于飞,李正甲,安芸蕾,高鹏,钟良枢,孙予罕..合成气催化转化直接制备低碳烯烃研究进展[J].燃料化学学报,2016,44(7):801-814,14.基金项目
The project was supported by the National Natural Science Foundation of China (21403278,21573271,91545112) and Shanghai Municipal Science and Technology Commission, China (15DZ1170500).国家自然科学基金(21403278,21573271,91545112)和上海市科委项目(15DZ1170500)资助 （21403278,21573271,91545112）
