聚合离子液体磷钨酸盐合成及催化模拟油氧化脱硫OA北大核心CSCDCSTPCD
Synthesis of P/W-coupled polyionic liquids for oxidative desulfurization of model oil
合成了新型的聚合离子液体磷钨酸盐(聚1-丁基-3-乙烯基咪唑磷钨酸盐)( PBVImPW),采用FT-IR、XRD和 TG进行表征,通过CHN元素和ICP分析确定其结构。催化剂用于过氧化氢为氧化剂的模拟油品氧化脱硫反应。考察反应温度、氧硫比、催化剂用量等对脱硫率的影响。结果表明,当反应温度为50益,n(H2O2)/n(S)为8,n (PBVImPW (P))/n (BT)为0.4：1.0,反应时间150 min时,苯并噻吩(BT)的转化率可以达到…查看全部>>
A novel PW-coupled polyionic liquid ( 1-n-butyl-3-vinylimidazolium phosphotungstate ) ( PBVImPW) was successfully synthesized and characterized by FT-IR, XRD, TG, ICP and CHN analysis. The prepared catalyst was applied in oxidative desulfurization processes of the model oil in the presence of H2 O2 . Several parameters including temperature, time, the amount of hydrogen peroxide and catalyst were investigated. PBVImPW is proved to be a highly efficient catal…查看全部>>
苑丹丹;宋华林;由曼玉;宋华
东北石油大学 化学化工学院，黑龙江 大庆 163318 东北石油大学 石油与天然气化工省重点实验室，黑龙江 大庆 163318牡丹江医学院 医学影像学院，黑龙江 牡丹江 157011东北石油大学 化学化工学院，黑龙江 大庆 163318
化学
聚合离子液体磷钨酸氧化脱硫
polyionic liquidsphosphotungstic acid (HPW)oxidative desulfurization(ODS)
《燃料化学学报》 2016 (7)
高活性磷化镍催化剂的设计制备及其深度加氢脱硫活性调控机制
876-881,6
The project was supported by National Natural Science Foundation of China (21276048), Project of Education Department of Heilongjiang Province (12541080), Guiding Science and Technology Project of Daqing (szdfy-2015-01) and Foster Fund Projects of Northeast Petroleum University (NEPUPY-1-09).国家自然科学基金(21276048),黑龙江省教育厅项目(12541080),大庆市指导性科技计划项目(szdfy-2015-01)和东北石油大学培育基金项目(NEPUPY-1-09)资助
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