中南民族大学学报（自然科学版）2016，Vol.35Issue(2)：15-18,4.
9，10-菲醌选择性溴化反应研究
Selective Bromination of 9,10 Phenanthrenequinone
摘要
Abstract
A series of 9,10-phenanthrenequinone bromides were selectively synthesized by varying reaction conditions such as the molar ratio of reactants , the type of solvent and the reaction temperature .2-bromine-9,10-phenanthrenequinone was prepared by mixing 9,10-phednanthrenequinone with N-bromobutanimide in a molar ratio of 1.0∶1.4 at 0 ℃ for 3 h with concentrated sulfuric acid as solvent , and a 60%yield was obtained.Under similar condition, 76%yield of 2,7-dibromo-9,10-phenanthrenequinone was obtained with a molar ratio of 9, 10-phenanthrenequinone to N-bromobutanimide of 1.0∶2.3 at room temperature.85% yield of 3-bromine-9, 10-phenanthrenequinone was prepared by mixing 9, 10-phednanthrenequinone and bromine in a molar ratio of 1.0∶1.4 at 106 ℃for 3 h with acetic acid as solvent , and benzoyl peroxide as initiating agent .90%yield of 3,6-dibromo-9,10-phenanthrenequinone was obtained with the molar ratio of 9, 10-phenanthrenequinone to bromine of 1.0∶3.4 at the same condition. The selective bromination of 9, 10-phenanthrenequinone was discussed and it was found that the amount of brominating reagent was the major factor determining the production of monobromide or dibromide .关键词
9,10-菲醌/菲醌溴代衍生物/溴化反应/溴化剂/选择性Key words
9,10-phenanthrenequinone/bromo-derivation/bromination reaction/brominating agent/selective分类
化学化工引用本文复制引用
杨汉民,沈千艳,刘长玉,郑文,陶俊..9，10-菲醌选择性溴化反应研究[J].中南民族大学学报（自然科学版）,2016,35(2):15-18,4.基金项目
国家自然科学基金资助项目 （）
