化工学报2016，Vol.67Issue(8)：3160-3169,10.DOI:10.11949/j.issn.0438-1157.20160352
水热处理过程中Y分子筛的骨架脱铝、补硅及二次孔的形成
Dealumination, silicon reinsertion, and secondary pore formation in steaming of zeolite Y
摘要
Abstract
Zeolite Y is one of the most important solid acids in the field of heterogeneous catalysis in the past, present and even for a long time in the future. The ultra-stable Y zeolites are the most important form for practical applications. The present review briefly summarized the structure changes of Y zeolite framework under steaming environment, including the removal of framework aluminum, the repair of framework vacancies by migrating silicon insertion, the generation of extra-framework aluminum and the formation of mesopores in the volume of zeolite grains. The emphasis of the present review was on the recent experimental and theoretical progresses about steaming dealumination. The necessity to continue conducting in-depth study on the post-synthesis modification of zeolite Y was stressed.关键词
分子筛/水热/脱铝/传递/介孔Key words
zeolite/steaming/dealumination/transport/mesopores分类
能源科技引用本文复制引用
覃正兴,申宝剑..水热处理过程中Y分子筛的骨架脱铝、补硅及二次孔的形成[J].化工学报,2016,67(8):3160-3169,10.基金项目
国家重点基础研究发展计划项目（2012CB215001）；国家自然科学基金项目（U1462202）。@@@@supported by the National Basic Research Program of China (2012CB215001) and the National Natural Science Foundation of China (U1462202) （2012CB215001）
