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微电解-Fenton氧化-絮凝组合工艺处理油田压裂废水

王顺武 李子旺 赵晓非 于庆龙

化工环保2016,Vol.36Issue(4):434-438,5.
化工环保2016,Vol.36Issue(4):434-438,5.DOI:10.3969/j.issn.1006-1878.2016.04.015

微电解-Fenton氧化-絮凝组合工艺处理油田压裂废水

Treatment of oilfield fracturing wastewater by combination process of micro-electrolysis-Fenton oxidation-flocculation

王顺武 1李子旺 1赵晓非 1于庆龙2

作者信息

  • 1. 东北石油大学 化学化工学院 石油与天然气化工黑龙江省重点实验室,黑龙江 大庆 163318
  • 2. 中国石油 大庆油田有限责任公司 第四采油厂,黑龙江 大庆 163511
  • 折叠

摘要

Abstract

The oilfield fracturing wastewater was treated by combination process of micro-electrolysis-Fenton oxidation-flocculation,and the process conditions were optimized. The experimental results show that:Under the optimum process conditions of initial wastewater pH 3.0,iron filings dosage 1.5 g/L(the mass ratio of iron filings to activated carbon is 1∶1),micro-electrolysis time 80 min,Fenton oxidation time 120 min,H2O2 dosage 940 mg/L and cationic polyacrylamide dosage 120 mg/L,the wastewater COD is dropped from 3 116.0 mg/L to 681.3 mg/L with 78.1% of total COD removal rate and 33.1%,37.9%,7.1% of COD removal rate of the three processes respectively, and the effluent water quality meets the on-site injection standardof SY/T 5329-2012;The treatment effect of the combination process is much better than that of micro-electrolysis,Fenton oxidation or flocculation process,and the process is a simple method with high utilization rate of chemical reagents.

关键词

压裂废水/微电解/Fenton氧化/絮凝/COD去除率

Key words

fracturing wastewater/micro-electrolysis/Fenton oxidation/flocculation/COD removal rate

分类

资源环境

引用本文复制引用

王顺武,李子旺,赵晓非,于庆龙..微电解-Fenton氧化-絮凝组合工艺处理油田压裂废水[J].化工环保,2016,36(4):434-438,5.

基金项目

黑龙江省教育厅科学技术研究项目(12531061) (12531061)

化工环保

OA北大核心CSCDCSTPCD

1006-1878

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