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溴氧化铋/石墨烯可见光下光催化氧化脱硫的研究

孙波 余雪 王亮 冯丽娟 李春虎

燃料化学学报2016,Vol.44Issue(9):1074-1081,8.
燃料化学学报2016,Vol.44Issue(9):1074-1081,8.

溴氧化铋/石墨烯可见光下光催化氧化脱硫的研究

Enhanced visible light photocatalytic oxidative desulfurization by BiOBr-graphene composite

孙波 1余雪 1王亮 1冯丽娟 1李春虎1

作者信息

  • 1. 中国海洋大学 海洋化学化工学院 化学工程与技术教育部重点实验室,山东 青岛 266100
  • 折叠

摘要

Abstract

A series of BiOBr-graphene photocatalysts was synthesized using hydrothermal method, and were characterized by X-ray diffraction (XRD), scanning electron microscopy ( SEM), transmission electron microscopy ( TEM), Raman spectroscopy, ultraviolet-visible diffuse reflection spectroscopy ( DRS) and photoluminescence ( PL) emission spectroscopy. The photocatalysts were evaluated for photocatalytic oxidative desulfurization of model oil. The optimal temperature, graphene loading and the amount of hydrogen peroxide ( H2 O2 ) were investigated. The oxidation reactivity of the different sulfur compounds was found to be in the order of DBT>4, 6-DMDBT>BT. Moreover, the mechanism of photocatalytic oxidation of DBT by BiOBr-graphene was proposed based on the present experimental results.

关键词

溴氧化铋/石墨烯/光催化氧化/二苯并噻吩/脱硫

Key words

BiOBr-graphene/photocatalytic oxidation/DBT/desulfurization

分类

化学化工

引用本文复制引用

孙波,余雪,王亮,冯丽娟,李春虎..溴氧化铋/石墨烯可见光下光催化氧化脱硫的研究[J].燃料化学学报,2016,44(9):1074-1081,8.

燃料化学学报

OA北大核心CSCDCSTPCD

2097-213X

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