燃料化学学报2016，Vol.44Issue(9)：1131-1137,7.
不同方法制备的介孔Ni/MgO催化剂上水蒸气重整苯酚制氢
Steam reforming of phenol for producing hydrogen over nickel support on MgO prepared by different methods
摘要
Abstract
MgO-supported nickel catalysts were prepared by impregnation and hydrothermal coprecipitation methods;they were characterized by XRD, N2 sorption, H2-TPR, TEM and TG and used in the steam reforming of biomass oil model compound-phenol for hydrogen production. The results indicated that the NiO/MgO solid solution prepared by the impregnation method displays higher surface area (60. 6 m2/g) and larger pore diameter (10. 1 nm), in comparison with that prepared by hydrothermal coprecipitation. After reduction, the mesoporous Ni/MgO catalyst obtained from impregnation exhibits small and uniform Ni nanoparticles ( 5 . 0-6 . 0 nm ) with high dispersion ( 19 . 44%) . As high surface area is favorable for the dispersion of Ni nanoparticles and mesoporous structure can promote the mass transfer of reactants and products, the Ni/MgO catalyst exhibits high activity as well as excellent coke resistance ability and long-term stability in the steam reforming of phenol.关键词
介孔MgO/Ni/MgO催化剂/水蒸气重整/苯酚/氢气Key words
mesoporous MgO/Ni/MgO catalyst/steam reforming/phenol/hydrogen分类
化学引用本文复制引用
纪婷婷,杨晓萱,王亚晶,王玉和..不同方法制备的介孔Ni/MgO催化剂上水蒸气重整苯酚制氢[J].燃料化学学报,2016,44(9):1131-1137,7.基金项目
The project was supported by Overseas Scholars Program of Department of Education, Heilongjiang Province (1155h019) and Program for Scientific and Technological Innovation Team Construction in University of Heilongjiang Province (2011TD010).黑龙江省教育厅海外学人科研项目(1155h019)和黑龙江省高等学校科技创新团队建设计划项目(2011TD010)资助 （1155h019）
