郑州大学学报（理学版）2016，Vol.48Issue(3)：99-102,4.DOI:10.13705/j.issn.1671-6841.2016048
三维镉超分子配合物的合成、晶体结构及热性能
Synthesis, Crystal Structure and Thermal Properties of a 3 D Cd(Ⅱ) Supramolecule Complex
摘要
Abstract
By employing 2-( p-fluorophenyl)-1H-imidazole-4,5-dicarboxylic acid ( p-FPhH3IDC) and 2,2′-bipy,to react with cadmium(Ⅱ) ion, a new supramolecule [Cd(p-FPhH2IDC)2 (2,2′-bipy)] ( complex 1) was successfully synthesized. Complex 1 was characterized by elemental analysis, IR spec-troscopy and single crystal X-ray diffraction. In complex 1, the [Cd(p-FPhH2IDC)2(2,2′-bipy)] units were joined through intermolecular hydrogen bonds to form a 1D chain. Then the 2D sheets were formed by π-πinteractions between the chains. Finally, these sheets were piled up into a 3D solid-state structure by the strong intermolecular interactions. Complex 1 indicated good thermal stability below 345. 5 ℃.关键词
咪唑二羧酸/镉(Ⅱ)/超分子/晶体结构/热性能Key words
imidazole dicarboxylate/Cd(Ⅱ)/supramolecule/crystal structure/thermal property分类
化学化工引用本文复制引用
刘爱玲,焦彦斌,王琦,侯立芬,李纲..三维镉超分子配合物的合成、晶体结构及热性能[J].郑州大学学报（理学版）,2016,48(3):99-102,4.基金项目
国家自然科学基金资助项目(J1210060) （J1210060）
