固体火箭技术2016，Vol.39Issue(4)：569-573,5.DOI:10.7673/j.issn.1006-2793.2016.04.022
新型锆硅复相陶瓷先驱体的制备及性能
Preparation and properties of new composite ceramic precursor containing zirconium and silicon
摘要
Abstract
The new composite ceramic precursor( ZPCSN) containing zirconium and silicon was prepared by blending tetrakis ( dimethylamido) zirconium( TDEZAZ) with phenylacetylene( PCSN) . The structure of ZPCSN was characterized by FT⁃IR;the cu⁃ring behavior of ZPCSN was analyzed by DSC and its thermal stability was studied by TGA;its ceramization performance was inves⁃tigated by XRD with XPS. The results show that ZPCSN can form dense three⁃dimensional network structure by cross⁃linking in cu⁃ring process and possess excellent heat resistance owing to the alkynyl in the molecular structure;in addition, ZPCSN can turn into multiple complex phases ceramics composed of ZrC, ZrN, SiC and Si3 N4 with a yield of 67.92%after sintering at 1 600℃ in argon, thus it indicates that ZPCSN exhibits excellent ceramization performance.关键词
先驱体/耐高温陶瓷/陶瓷化性能Key words
precursor/ultra high temperature ceramic/ceramization performance分类
航空航天引用本文复制引用
鲍潮军,宋宁,陈麒,倪礼忠..新型锆硅复相陶瓷先驱体的制备及性能[J].固体火箭技术,2016,39(4):569-573,5.基金项目
国家自然科学基金资助项目（51073053）。 （）
