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高炉渣制备系列精细化工品的技术研究

申星梅 李辽沙 武杏荣 王平 褚亮

化工学报2016,Vol.67Issue(9):3988-3994,7.
化工学报2016,Vol.67Issue(9):3988-3994,7.DOI:10.11949/j.issn.0438-1157.20160220

高炉渣制备系列精细化工品的技术研究

Preparation of a series of fine chemicals by blast furnace slag

申星梅 1李辽沙 2武杏荣 1王平 3褚亮3

作者信息

  • 1. 安徽工业大学教育部冶金减排与资源综合利用重点实验室,安徽马鞍山 243002
  • 2. 安徽工业大学冶金工程与资源综合利用安徽省重点实验室,安徽马鞍山 243002
  • 3. 安徽工业大学冶金工程与资源综合利用安徽省重点实验室,安徽马鞍山 243002
  • 折叠

摘要

Abstract

On the basis of previous works, preparation of a series of fine chemicals by blast furnace slag was researched further and deeply, and the process route was developed. The first product, gypsum, was obtained by sulphuric acid hydrolysis. The optimum conditions for preparing aluminum silicate were: water-slag ratio 7:1, pH 4.0 and adding small pieces of Al plates to remove iron. The optimum conditions for preparing magnesium aluminum spinel were: mass percent of urea 65% and amount of Na2S2O4 5%. The chemical composition of the three products was in accord with the relative standards.This process had the advantages of short flow, low cost, etc. Almost all valuable contents in the slag were used, and no residue was discharged. Thus, it had better environmental benefit.

关键词

高炉渣/超细硅酸铝/镁铝尖晶石/石膏/除铁率

Key words

blast furnace slag/aluminum silicate/magnesium aluminum spinel/gypsum/iron removal rate

分类

化学化工

引用本文复制引用

申星梅,李辽沙,武杏荣,王平,褚亮..高炉渣制备系列精细化工品的技术研究[J].化工学报,2016,67(9):3988-3994,7.

基金项目

国家自然科学基金项目(51302003,51274006);安徽省科技厅项目(1506c085003);安徽省冶金固废材料化利用新技术创新团队项目;2014年马鞍山市科技计划。@@@@ supported by National Natural Science Foundation of China (51302003,51274006), Anhui Science & Technology Department Foundation of China (1506c085003), Anhui Innovation Team Project of New Technology in Materialization of Metallurgical Solid Wastes and Ma’anshan Science & Technology Foundation of 2014 (51302003,51274006)

化工学报

OA北大核心CSCDCSTPCD

0438-1157

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