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001×8树脂从离子型稀土浸出液中吸附稀土及杂质离子的性能研究

管新地 沈文明 张胜其 张剑 蓝桥发 杨幼明

有色金属科学与工程2016,Vol.7Issue(4):134-139,6.
有色金属科学与工程2016,Vol.7Issue(4):134-139,6.DOI:10.13264/j.cnki.ysjskx.2016.04.023

001×8树脂从离子型稀土浸出液中吸附稀土及杂质离子的性能研究

Property of 001×8 resin for adsorption RE 3+and impurity ions from ionic-type rare earth lixivium

管新地 1沈文明 1张胜其 1张剑 1蓝桥发 2杨幼明1

作者信息

  • 1. 江西理工大学冶金与化学工程学院,江西 赣州 341000
  • 2. 国家离子型稀土资源高效开发利用工程技术研究中心,江西 赣州 341000
  • 折叠

摘要

Abstract

To reveal the regulations of adsorption capacity and separation coefficient during the adsorption of RE3+and impurity ions from ionic-type rare earth lixivium, the effect of temperature, pH value, dilution ration and flow velocity were investigated through static and dynamic adsorption experiments. The results show that the adsorption capacity and separation coefficient tends to increase first then decrease with the increasing of pH, and reaches maximum at pH 3.5. Adsorption capacity increases with the rising of temperature and tends to be balanced after 313 K. The adsorption capability order of 001×8 resin to all related ions is: RE3+>Al3+>Mg2+>SiO32-. The adsorption capacity to RE3+, SiO32-and Al3+is proportional to desaturation multiple, and inverse ratio to flow velocity. Mg2+ adsorption reduces with the increase of desaturation multiple or flow velocity. Thus increase of desaturation multiple and decrease of flow velocity are beneficial to the rare earth adsorption capacity and impurities removing capacity of 001×8 resin.

关键词

001×8树脂/离子型稀土/吸附量/分离系数

Key words

001×8 resin/ionic-type rare earth/adsorption capacity/separation coefficient

分类

化学化工

引用本文复制引用

管新地,沈文明,张胜其,张剑,蓝桥发,杨幼明..001×8树脂从离子型稀土浸出液中吸附稀土及杂质离子的性能研究[J].有色金属科学与工程,2016,7(4):134-139,6.

基金项目

国家高技术研究发展计划(863计划)资助项目(2012AA061901) (2012AA061901)

有色金属科学与工程

OACSTPCD

1674-9669

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