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三维网状石墨烯修饰二氧化钛光催化剂的制备及性能研究

孙云飞 班建民 罗恒 陶重犇 孙建东 唐波

苏州科技学院学报(自然科学版)2016,Vol.33Issue(3):48-53,6.
苏州科技学院学报(自然科学版)2016,Vol.33Issue(3):48-53,6.

三维网状石墨烯修饰二氧化钛光催化剂的制备及性能研究

Preparation and application of TiO 2 composite photocatalyst modified by three-dimensional network graphene

孙云飞 1班建民 1罗恒 1陶重犇 1孙建东 2唐波3

作者信息

  • 1. 苏州科技大学 电子与信息工程学院,江苏 苏州 215009
  • 2. 中科院苏州纳米技术与纳米仿生研究所 纳米器件与应用重点实验室,江苏 苏州 215123
  • 3. 常州大学 石油工程学院,江苏 常州 213016
  • 折叠

摘要

Abstract

With the gradually increased environmental protection standard, the TiO 2 based photocalalyst becomes a hot issue. The TiO2 composite photocatalyst modified by graphene has attracted more and more attention due to the large BET area and excellent electron transport ability of graphene, which endows the graphene not only act-ing as carrier for TiO2 nanoparticles, but also rapid electron transport network for the resulting composites. In this study, three-dimensional network graphene prepared by chemical vapor deposition approach was adopted to pre-pare composite photocatalyst with TiO2 via hydrothermal progress. The BET area of the fabricated photocatalyst is as high as 390 m2·g-1, indicating outstanding absorbility for the pollution molecules. The degradation rate con-stant of methyl orange reaches 8.1×10-2 min-1 and 2.8×10-2 min-1 under UV-light and visible-light irradiation, re-spectively. The rate constant under UV-light irradiation is 200% higher than that of using pure TiO 2. Moreover, the photocatalyst displays favorable stability after 10 cycle use, manifesting promising application prospect.

关键词

三维网状石墨烯/复合光催化剂/可见光活性

Key words

three-dimensional network graphene/composite photocatalyst/visible-light activity

分类

化学化工

引用本文复制引用

孙云飞,班建民,罗恒,陶重犇,孙建东,唐波..三维网状石墨烯修饰二氧化钛光催化剂的制备及性能研究[J].苏州科技学院学报(自然科学版),2016,33(3):48-53,6.

基金项目

国家自然科学基金青年基金资助项目(61401297;50156012;61401456);江苏省自然科学基金青年基金资助项目(BK20140283;BK20150266);常州市基础研究科技资助计划(CJ20159032);常州大学科技启动基金资助项目 ()

苏州科技学院学报(自然科学版)

2096-3289

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