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氯化铯甲醇溶液对有机聚合物太阳能电池的影响

文颖秀 刘统方 朱丽杰 王越 邓振波

发光学报2016,Vol.37Issue(9):1097-1102,6.
发光学报2016,Vol.37Issue(9):1097-1102,6.DOI:10.3788/fgxb20163709.1097

氯化铯甲醇溶液对有机聚合物太阳能电池的影响

Influence of Cesium Chloride Methanol Solution on The Conventional Organic Polymer Solar Cells

文颖秀 1刘统方 1朱丽杰 1王越 1邓振波1

作者信息

  • 1. 北京交通大学光电子技术研究所 发光与光信息技术教育部重点实验室,北京 100044
  • 折叠

摘要

Abstract

The cesium chloride ( CsCl) methanol solution was introduced into the conventional or-ganic polymer solar cells as cathode buffer layer to improve its properties. The charge accumulation between the Al cathode and PTB7/PC70 BM was analyzed through capacitance-voltage ( C-V) meas-urement and the change of work function of Al was investigated by ultraviolet photoelectron spectros-copy (UPS). The results show that the short-circuit current (Jsc), the open-circuit voltage (Voc), the fill factor and the power conversion efficiency ( PCE) of the device with the CsCl methanol solu-tion treatment have been improved. And the PCE reaches 6. 36%, which has been improved 11%compared with the methanol treatment devices and 42 . 6% compared with the devices without any treatment. This one-step solution treatment can improve the device properties by reducing the charge accumulation and decreasing the work function of Al cathode which is benefit to electron collection.

关键词

氯化铯/甲醇/聚合物太阳能电池/电荷积累/功函数

Key words

cesium chloride/methanol/polymer solar cells/charge accumulation/work function

分类

数理科学

引用本文复制引用

文颖秀,刘统方,朱丽杰,王越,邓振波..氯化铯甲醇溶液对有机聚合物太阳能电池的影响[J].发光学报,2016,37(9):1097-1102,6.

基金项目

中央高校基本科研业务费专项资金(2014JBZ009);国家自然科学基金(61274063,61377028,61475014,61475017)资助项目 (2014JBZ009)

发光学报

OA北大核心CSCDCSTPCD

1000-7032

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