烟草科技2016，Vol.49Issue(9)：42-49,8.DOI:10.16135/j.issn1002-0861.2016.0056
在线GPC-GC-MS/MS法直接检测烟叶中的农药残留
Determination of pesticide residues in tobacco by on-line gel permeation chromatography-gas chromatography/tandem mass spectrometry
罗彦波 1李翔宇 1朱风鹏 1张洪非 1姜兴益 1李雪 1庞永强1
作者信息
- 1. 国家烟草质量监督检验中心，郑州高新技术产业开发区枫杨街2号 450001
- 折叠
摘要
Abstract
In order to analyze the pesticide residues in tobacco leaves, tobacco extract was directly analyzed by on-line gel permeation chromatography-gas chromatography-tandem mass spectrometry. This method was able to quantify the residue levels of 31 pesticides, and the optimal determination conditions were obtained via optimizing gel permeation chromatography collection time and multiple reaction monitoring parameters, which could influence the determination results. The results showed that: 1)Under the optimized conditions, the limits of detection of the method for the target analytes ranged from 1.95 to 212 ng/L, the determination coefficients (R2) were more than 0.99 for all the target analytes, the intra- and inter-day relative standard deviations were no more than 6.3% and 10.2%, respectively; and the recoveries of standard were from 82.2% to 121.5% for test samples. 2) The method was successfully applied to the analysis of pesticide residues in tobacco samples, the test results well agreed with those of existing standard methods.关键词
烟叶/农药残留/在线凝胶渗透色谱-气相色谱-串联质谱(在线GPC-GC-MS/MS)/直接检测Key words
Tobacco leaf/Pesticide residue/On-line gel permeation chromatography-gas chromatography/tandem mass spectrometry(On-line GPC-GC-MS/MS)/Direct determination分类
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罗彦波,李翔宇,朱风鹏,张洪非,姜兴益,李雪,庞永强..在线GPC-GC-MS/MS法直接检测烟叶中的农药残留[J].烟草科技,2016,49(9):42-49,8.
