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X65管线钢在沉积物下腐蚀与缓蚀剂作用效果

徐云泽 黄一 盈亮 王晓娜 杨飞

材料工程2016,Vol.44Issue(10):100-108,9.
材料工程2016,Vol.44Issue(10):100-108,9.DOI:10.11868/j.issn.1001-4381.2016.10.015

X65管线钢在沉积物下腐蚀与缓蚀剂作用效果

Corrosion of X65 Pipeline Steel Under Deposit and Effect of Corrosion Inhibitor

徐云泽 1黄一 1盈亮 2王晓娜 3杨飞1

作者信息

  • 1. 大连理工大学船舶与海洋工程学院,辽宁大连116024
  • 2. 大连理工大学材料科学与工程学院,辽宁大连116024
  • 3. 大连理工大学物理与光电工程学院,辽宁大连116024
  • 折叠

摘要

Abstract

Effect of the deposit on the electrochemical parameters of X 65 pipeline steel in oxygen con‐tained sodium chloride solution was studied by EIS and PDS methods .The galvanic corrosion behavior under deposit and effect of different concentration of corrosion inhibitor PBTCA were studied by elec‐trical resistance (ER) method combined with ZRA .The results show that the corrosion potential of X65 steel shifts negatively as SiO2 covering its surface and the corrosion rate becomes lower .When the galvanic couple specimen with deposit is electrically connected with the specimen without deposit , anodic polarization occurs on X65 steel under deposit and the galvanic current density decreases from 120μA/cm2 to 50μA/cm2 and keeps stable .As 5 × 10-5 ,8 × 10-5 and 3 × 10-4 PBTCA were introduced into the solution ,the galvanic current density reaches the highest 1300μA/cm2 and then decreases to 610μA/cm2 keeping stable around 610μA/cm2 , corrosion rate of X65 steel under deposit reaches 6.11mm/a .PBTCA accelerates the corrosion of X65 steel under deposit in oxygen contained solution . Through the investigation on the surface of the specimens ,serious local corrosion occurs on the X65 steel surface under deposit .

关键词

X65管线钢/沉积物下腐蚀/PBTCA/电偶腐蚀

Key words

X65 pipeline steel/under deposit corrosion/PBTCA/galvanic corrosion

分类

矿业与冶金

引用本文复制引用

徐云泽,黄一,盈亮,王晓娜,杨飞..X65管线钢在沉积物下腐蚀与缓蚀剂作用效果[J].材料工程,2016,44(10):100-108,9.

基金项目

“十二五”国家重大科技专项(2011ZX05056);国家自然科学基金(11201023);中国博士后科学基金 ()

材料工程

OA北大核心CSCDCSTPCD

1001-4381

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