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高铝粉煤灰提铝硅钙渣制备硅灰石微晶玻璃研究

陈建 马鸿文 蒋周青 张盼

硅酸盐通报2016,Vol.35Issue(9):2898-2903,6.
硅酸盐通报2016,Vol.35Issue(9):2898-2903,6.

高铝粉煤灰提铝硅钙渣制备硅灰石微晶玻璃研究

Preparation of Wollastonite Glass-ceramics by Using Silicate-calcium Slag Generated in Process of Extracting Alumina from High-alumina Fly Ash

陈建 1马鸿文 2蒋周青 3张盼1

作者信息

  • 1. 中国地质大学 北京 非金属矿物与固废资源材料化利用北京市重点实验室,北京 100083
  • 2. 中国地质大学 北京 材料科学与工程学院,北京 100083
  • 3. 昊青薪材 北京 技术有限公司,北京 100083
  • 折叠

摘要

Abstract

The silicate-calcium slag generated in process of extracting alumina from high-alumina fly ash was used as the main raw material to prepared wollastonite glass-ceramics by sintering method .The effect of amount of silicate-calcium slag additions and heat treatment conditions on crystallization process , microstructures and properties of the prepared glass-ceramics were studied by differential thermal analysis (DTA), X-ray diffraction (XRD) and scanning electron microscopy (SEM) methods.The results indicate that prolong nucleation time and crystallization time could help to wollastonite crystal orientation grown up and closely arranged , and have a significant influence on mechanical properties of glass-ceramics, while the crystallization temperature and nucleation temperature have relatively small influence .With the amount of silicate-calcium slag increasing , wollastonite precipitation from matrix glass is enhancing and signal crystal phase of wollastonite glass-ceramics were prepared under the conditions of add 70 .98%silicate-calcium slag in raw material on the conditions of heat treating at 800 ℃for 90 min followed by crystallization at 920 ℃for 90 min.

关键词

硅钙渣/硅灰石/微晶玻璃/粉煤灰

Key words

silicate-calcium slag/wollastonite/glass-ceramics/fly ash

分类

化学化工

引用本文复制引用

陈建,马鸿文,蒋周青,张盼..高铝粉煤灰提铝硅钙渣制备硅灰石微晶玻璃研究[J].硅酸盐通报,2016,35(9):2898-2903,6.

基金项目

中央高校基本科研业务费 ()

硅酸盐通报

OA北大核心CSCDCSTPCD

1001-1625

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