天津科技大学学报2016，Vol.31Issue(5)：14-18,5.DOI:10.13364/j.issn.1672-6510.20150179
分子印迹传感器对标本中塑化剂直接快速检测
Quick Detection of DINP in Samples by Molecular Imprinted Sensor
摘要
Abstract
An electrochemical sensor based on molecularly imprinted sensor for quick detection of DINP was developed in this research.Firstly,imprinted polymer particles(MIPs)were prepared through thermal polymerization.Then,MIPs and agarose were mixed in proportion.The electrochemical sensor for DINP was fixed by the mixture on a glassy carbon elec-trode.The sensor can be combined with the template molecule DINP and its electrochemical signals are influenced by DINP concentration.Thus,it could be used to detect DINP levels in samples,and DINP concentration was quickly detected in wine samples without sample pretreatment.The linear equation in this study wasΔI=0.03c+3.07,the correlation coefficient is R2=0.998,the linear range was 5×10-8-1×10-6,mol/L,the sensitivity limit was 2.7×10-8,mol/L,and the recovery rate was 105.3%,-115.7%,.关键词
邻苯二甲酸二异壬酯/分子印迹聚合物颗粒/电化学传感器/检测/循环伏安Key words
diisononyl phthalate/molecularly imprinted polymer particles/electrochemical sensor/detection/cyclic voltammetry分类
化学化工引用本文复制引用
陶强,张娟琨,刘英姿,鞠小翠,左娟娟..分子印迹传感器对标本中塑化剂直接快速检测[J].天津科技大学学报,2016,31(5):14-18,5.基金项目
国际合作项目(14RCCFSF00140) （14RCCFSF00140）
