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水滑石-石墨烯复合物用于CO甲烷化

刘竞舸 刘源 郝庆兰

天津科技大学学报2016,Vol.31Issue(5):35-41,7.
天津科技大学学报2016,Vol.31Issue(5):35-41,7.DOI:10.13364/j.issn.1672-6510.20150246

水滑石-石墨烯复合物用于CO甲烷化

LDH-graphene Compositions for CO Methanation

刘竞舸 1刘源 2郝庆兰1

作者信息

  • 1. 天津科技大学化工与材料学院,天津 300457
  • 2. 天津大学化工学院,天津 300072
  • 折叠

摘要

Abstract

Layered double hydroxide (LDH)-graphene compound was prepared as a precursor for CO methanation. Due to its high thermal conductivity,graphene was used in this research to improve the catalytic anti-sintering property. The results showed that most LDH adhered to the graphenen in the Ni-Al2O3/5%rGO catalyst,but some LDH was covered by graphene layers with large surface area,which caused the crystallinity decrease. After reduction,some of the active particles may be enveloped and could not take part in the reaction of CO methanation. Ni-Al2O3/5%rGO showed inferior catalytic perform-ance,but its thermal stability improved obviously. During the stability test,CO conversion of Ni-Al2O3/5%rGO maintained at 100%for 50 h.

关键词

水滑石/石墨烯/一氧化碳/甲烷化/抗烧结

Key words

layered double hydroxides/graphene/CO/methanation/anti-sintering

分类

化学化工

引用本文复制引用

刘竞舸,刘源,郝庆兰..水滑石-石墨烯复合物用于CO甲烷化[J].天津科技大学学报,2016,31(5):35-41,7.

基金项目

国家自然科学基金资助项目(21376170) (21376170)

天津科技大学学报

OA北大核心CSTPCD

1672-6510

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