固体火箭技术2016，Vol.39Issue(5)：697-702,6.DOI:10.7673/j.issn.1006-2793.2016.05.018
含硅芳炔单体的流变性及聚合物热分解
Rheological property of silicon-containing arylacetylenes and thermal degradation of their polymers
摘要
Abstract
The rheological properties of phenyl(triphenylethynyl)silane(PTPES), vinyl(triphenylethynyl)silane(VTPES), diphenyl(diphenylethynyl)silane(BPBPES) three monomers and their polymers(TSAR) were studied by rheometer. At the same time, the degradation reaction kinetics of TSAR was analyzed and the degradation mechanism was also proposed by kinetic theory. The results show that three monomers have an excellent processability with beyond 150 ℃ process window by rheological analysis. Char yield obtained by TG was about 70% at 800℃. The reaction order was 4 and reaction activation energy was E=131.2 kJ/mol by 8 different kinetic analysis methods.关键词
苯基三苯乙炔基硅烷/乙烯基三苯乙炔基硅烷/二苯基二苯乙炔基硅烷/流变性能/反应动力学/热分解机理Key words
phenyl ( triphenylethynyl ) silane/vinyl ( triphenylethynyl ) silane/diphenyl ( diphenylethynyl ) silane/rheological properties/reaction kinetics/thermal degradation mechanism分类
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谭德新,徐远,王艳丽,疏瑞文,邢宏龙..含硅芳炔单体的流变性及聚合物热分解[J].固体火箭技术,2016,39(5):697-702,6.基金项目
国家自然科学基金（51477002；51303005）；安徽省高校自然科学基金重点项目（ KJ2013A087；KJ2013A095）；安徽理工大学博士基金。 （）
