天津工业大学学报2016，Vol.35Issue(5)：27-31,5.DOI:10.3969/j.issn.1671-024x.2016.05.005
基于2，3-吡嗪二酸和双三唑丁烷的锌配合物的合成及其晶体结构与性质
Synthesis, crystal structures and characterization of Zn metal complex with bis (1,2,4-triazol-1-yl) butane and 2,3-pyrazinedicarboxylic acid
摘要
Abstract
A novel two-dimensional wave-like Zn complex, formulated as{[Zn(pzdc)(btb)0.5(H2O)2]·H2O}n(H2pzdc=2, 3-pyrazinedicarboxylic acid, btb=bis(1, 2, 4-triazol-1-yl)butane), was synthesized by the self-assembly re-actions of btb and H2pzdc with zinc nitrates. X-ray diffraction analysis reveals that the complex displays a 3-con-nected (6, 3) topology. The central ZnI ions of the compound are assembled into 1D zigzag chains by pzdc2-anions, which are further linked by flexible btb bridges to form a special 2D wave-like layer. And a 3D supramolecular architecture is finally constructed by the iner-and intra-molecular hydrogen bonds of O-H…N and O-H…O. Luminescence and thermogravimetric analyses have also been investigated in detail.关键词
锌配合物/双三唑丁烷/2,3-吡嗪二酸/晶体结构Key words
zincmetal complex/bis(1, 2, 4-triazol-1-yl)butane/2, 3-pyrazinedicarboxylic acid/crystal structure分类
化学化工引用本文复制引用
夏军,崔振,龚小林,郑春明..基于2，3-吡嗪二酸和双三唑丁烷的锌配合物的合成及其晶体结构与性质[J].天津工业大学学报,2016,35(5):27-31,5.基金项目
国家自然科学基金项目资助 （）
