天然气化工2016，Vol.41Issue(5)：1-5,5.
聚甲醛二甲醚的绿色合成工艺研究
Environment-friendly process for synthesis of polyoxymethylene dimethyl ethers
隆宽燕 1王涛 1田恒水 1魏永梅1
作者信息
- 1. 华东理工大学化工学院，上海 200237
- 折叠
摘要
Abstract
The synthesis of polyoxymethylene dimethyl ethers (PODEn) from methanol and trioxymethylene catalyzed by macroporous strong acid resin HD-8 was studied. The optimum reaction conditions were determined by orthogonal experiments as follows: methanol/trioxymethylene molar ratio of 0.5, 110℃, 2MPa, 3h, and catalyst/feedstock mass ratio of 2.2%. Under above conditions, the selectivity and yield of PODE3-8 were 77.54%and 57.42%, respectively. The effects of reaction conditionss on reaction were investigated, and results show that it was in the sequence: methanol/trioxymethylene molar ratio > pressure > catalyst dosage >time>temperaure.关键词
聚甲醛二甲醚/HD-8/甲醇/三聚甲醛Key words
polyoxymethylene dimethyl ethers/HD-8/methanol/trioxymethylene分类
化学工程引用本文复制引用
隆宽燕,王涛,田恒水,魏永梅..聚甲醛二甲醚的绿色合成工艺研究[J].天然气化工,2016,41(5):1-5,5.
