环境工程学报2016,Vol.10Issue(10):5561-5567,7.DOI:10.12030/j.cjee.201512109
UV/O3降解水样中COD的动力学建模
Kinetics modeling for degradation of COD in water sample by UV/O3
摘要
Abstract
Kinetics modeling can be used to effectively analyze and predict the process of the degradation of organics using the UV/O3 technique.It can also be used to improve the removal rate and reduce power consumption;however,the methods of kinetics modeling that were reported previously cannot be applied when there are unknown organics in the sample solution.Based on the chemical reaction mechanism,a mathematic model that can predict the treatment of a water sample with unknown organic species was established by including the evolution of CO2.The sensitivity of the model was tested under a variety of digestion conditions.Meanwhile,a sample solution mixed with glucose,urea,and potassium acid phthalate was used to validate the accuracy of the model.The experimental and simulated results followed the same trend.关键词
高级氧化技术/动力学模型/羟基自由基/臭氧/反应级数/反应速率常数Key words
advanced oxidation processes/kinetics model/hydroxyl radical/ozone/reaction order/reaction rate constant分类
资源环境引用本文复制引用
余晓栋,杨慧中..UV/O3降解水样中COD的动力学建模[J].环境工程学报,2016,10(10):5561-5567,7.基金项目
中央高校基本科研业务费专项资金资助(JUSRP51510) (JUSRP51510)