高校化学工程学报2016，Vol.30Issue(5)：1112-1118,7.DOI:10.3969/j.issn.1003-9015.2016.05.018
N,N'-乙撑双硬脂酰胺的热分解动力学研究
Research on Thermal Decomposition Kinetics of N,N'-Ethylenebis (stearamide)
摘要
Abstract
Thermal decomposition characteristics and kinetics of N,N'-ethylenebis(stearamide) (EBS) were investigated under high purity nitrogen atmosphere by DTA-TGA techniques. The thermal decomposition kinetic parameters of EBS were calculated by Flynn-Wall-Ozawa, Kissinger and Šatava-Šesták methods, and the decomposition mechanism was also studied. The results show that the thermal decomposition process contains two stages at 519.15~723.15 K. For the first and second stages, the activation energies are 78.41 and 88.38 kJ . mol-1 respectively, and the pre-exponential factors are 2.188×108 and 7.586×108 min-1, respectively. Moreover, the integral equations for the decomposition mechanism of the two stages are g(α) = 1-(1-α)2 and g(α) = α, respectively. The data obtained provide fundamental information for industry production and application of EBS.关键词
N,N'-乙撑双硬脂酰胺/热分解/动力学/热失重-差热分析Key words
N,N'-ethylenebis (stearamide)/thermal decomposition/kinetics/TGA-DTA分类
化学化工引用本文复制引用
郄晶伟,李文俐,周彩荣..N,N'-乙撑双硬脂酰胺的热分解动力学研究[J].高校化学工程学报,2016,30(5):1112-1118,7.基金项目
河南省教育厅科技攻关重点项目(13A530721)。 （13A530721）
