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内蒙胜利褐煤腐殖酸对煤平衡复吸水的影响

刘红缨 郝国军 朱雨曦 杜倩倩 朱书全

燃料化学学报2016,Vol.44Issue(11):1281-1286,6.
燃料化学学报2016,Vol.44Issue(11):1281-1286,6.

内蒙胜利褐煤腐殖酸对煤平衡复吸水的影响

Effect of humic acid on equilibrium adsorption of water of Shengli lignite

刘红缨 1郝国军 1朱雨曦 1杜倩倩 1朱书全1

作者信息

  • 1. 中国矿业大学 北京 化学与环境工程学院,北京 100083
  • 折叠

摘要

Abstract

The effect of humic acid, an important component of lignite, on the water content in Shengli lignite was studied. The content of oxygen containing functional groups of humic acid in Shengli lignite was determined. The isothermal adsorption and desorption curves of the lignite, brown humic acid and the residual coal were analyzed. Further the primary and secondary site adsorption of the lignite, brown humic acid and the residual coal were studied. The results show that 2/5 carboxyl and 1/5 hydroxyl in Shengli lignite are provided by humic acid. The pore size and pore volume of brown humic acid are smaller than those of the lignite. So brown humic acid is unfavorable for the formation of water clusters. The humic acid is adverse to equilibrium adsorption of water for Shengli lignite.

关键词

褐煤/腐殖酸/平衡复吸附水含量/等温吸附

Key words

lignite/humic acid/equilibrium adsorption of water/isothermal adsorption

分类

矿业与冶金

引用本文复制引用

刘红缨,郝国军,朱雨曦,杜倩倩,朱书全..内蒙胜利褐煤腐殖酸对煤平衡复吸水的影响[J].燃料化学学报,2016,44(11):1281-1286,6.

基金项目

The project was supported by the Major State Basic Research Development Program of China (973 program,2012CB214901).国家重点基础研究发展规划(973计划,2012CB214901)资助 (973 program,2012CB214901)

燃料化学学报

OA北大核心CSCDCSTPCD

2097-213X

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