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促进剂对ENR25的硫化特性与耐空气老化性能的影响

杨昌金 罗勇悦 钟杰平 许逵 林宏图 彭政

合成材料老化与应用2016,Vol.45Issue(5):1-4,16,5.
合成材料老化与应用2016,Vol.45Issue(5):1-4,16,5.

促进剂对ENR25的硫化特性与耐空气老化性能的影响

Effect of Accelerators on Cure and Hot-air Aging Properties of Epoxidized Natural Rubber

杨昌金 1罗勇悦 1钟杰平 2许逵 1林宏图 1彭政1

作者信息

  • 1. 中国热带农业科学院农产品加工研究所,农业部热带作物产品加工重点实验室,广东湛江524001
  • 2. 广东海洋大学 理学院,广东湛江524088
  • 折叠

摘要

Abstract

The effects of three accelerators,such as N-tert-butyl-2-benzothiazyl sulphenamide (TBBS),2-mer-captobenzothiazole ( M) and tetramethylthiuram disulphide ( TMTD ) on cure characteristics, crosslink densities, mechanical properties and hot-air aging of epoxidized natural rubber with 25 mol % epoxidation ( ENR25 ) were studied. The results showed that the ENR25 with accelerator NS showed the longer scorch time and appropriate cure rate. Meanwhile TBBS gave the higher crosslink density,the best mechanical property,hot-air aging resistance and thermal-oxidative stability for ENR25. So the accelerator TBBS is the best choice for ENR25.

关键词

促进剂/环氧化天然橡胶/硫化/耐热空气老化/力学性能

Key words

accelerator/epoxidized natural rubber/cure/hot-air aging resistance/mechanical property

分类

化学化工

引用本文复制引用

杨昌金,罗勇悦,钟杰平,许逵,林宏图,彭政..促进剂对ENR25的硫化特性与耐空气老化性能的影响[J].合成材料老化与应用,2016,45(5):1-4,16,5.

基金项目

海南省自然基金资助(1312441) (1312441)

公益性行业(农业)科研专项经费资助(201403066) (农业)

合成材料老化与应用

OACSTPCD

1671-5381

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