化工学报2016，Vol.67Issue(11)：4541-4551,11.DOI:10.11949/j.issn.0438-1157.20160644
乙烯齐聚催化体系中的Friedel-Crafts烷基化反应研究进展
Progress of Friedel-Crafts alkylation reaction in catalyst system of ethylene oligomerization
摘要
Abstract
Using transition metal complexes to catalyse ethylene oligomerization is an important route for preparingα-olefins. The partially catalytic systems have entered the stage of pilot and industrial production. However, the recent researches have suggested that the oligomerization products of some transition metal catalysts in toluene solvent may react with toluene directly as Friedel-Crafts alkylation reaction, which could open a new way for the production of alkylbenzene. This paper reviews the progress of Friedel-Crafts alkylation reaction in ethylene oligomerization in recent years. The influence of the structure of catalysts, catalytic system and process conditions on the alkylation reaction is described in detail. Meanwhile, it gives the Friedel-Crafts alkylation reaction process in ethylene oligomerization, which would be of great significance to design the catalysts that could catalyse ethylene oligomerization to make mixed alkylbenzenes.关键词
催化/乙烯齐聚/催化剂/Friedel-Crafts烷基化/烷基苯/反应Key words
catalysis/ethylene oligomerization/catalyst/Friedel-Crafts alkylation/alkylbenzene/reaction分类
化学化工引用本文复制引用
王俊,侯爽,宋磊,王斯晗,李翠勤..乙烯齐聚催化体系中的Friedel-Crafts烷基化反应研究进展[J].化工学报,2016,67(11):4541-4551,11.基金项目
国家自然科学基金项目（21576048）；中国石油科技创新基金研究项目(2014D-5006-0503)。@@@@Foundation item:supported by the National Natural Science Foundation of China (21576048) and the PetroChina Innovation Foundation (2014D-5006-0503) （2014D-5006-0503）
