火炸药学报2016，Vol.39Issue(5)：74-78,5.DOI:10.14077/j.issn.1007-7812.2016.05.012
一水合双四唑乙烷氨基胍的制备及性能研究
Preparation and Properties of Bitetrazolyethane Aminoguanidine
摘要
Abstract
A new kind of high-nitrogen compound bitetrazolyethane aminoguanidine monohydrate(CH7N4·C4H4N8·H2O)was prepared by an one-pot method.Its single crystal was characterized by FT-IR spectroscopy and elemental analysis and the crystal structure is measured by X-ray single crystal diffractometry. Its thermal properties were measured by TG-DTG and DSC. Its non-isothermal kinetic parameters were calculated by using Kissinger′s method and Ozawa′s method. Its heat of combustion was tested through an oxygen bomb calorimetry. Its detonation velocity (D) and detonation pressure (P) were computed by K-J formula and the mechanical sensitivity was tested. The results show that the crystal is monoclinic, its space group is C2/c (No.15) with cell parameters of a=1.1261(2)nm, b=0.71062(14)nm, c=2.7241(5)nm, β=95.95(3)°,V=2.1682(8) nm3, Z=4, and the theoretical density is 1.527g/cm3. It has good thermal stability with initial decomposition temperature of 289.3℃. Its non-isothermal kinetic parameters, apparent activation energy is 219.05kJ/mol, lg(A/s-1) is 38.61.The heat of combustion and enthalpy of formation are 9.515MJ/kg and 2892.2kJ/mol, respectively. The detonation velocity and detonation pressure are 6.95km/s and 19.3GPa. The impact sensitivity is higher than 50cm, and friction sensitivity is 0, revealing that the compound has low mechanical sensitivity and good thermal stability.关键词
高氮含能化合物/一水合双四唑乙烷氨基胍/唑类含能盐/晶体结构/热稳定性/爆速/爆压Key words
high-nitrogen energetic compound/bitetrazolyethane aminoguanidine/azoles energetic salt/crystal structure/thermal stability/detonation velocity/detonation pressure分类
军事科技引用本文复制引用
张悦阳,冯永安,张博,杨利,张同来..一水合双四唑乙烷氨基胍的制备及性能研究[J].火炸药学报,2016,39(5):74-78,5.基金项目
爆炸科学与技术国家重点实验室基金(YDKT16-17) （YDKT16-17）
