厦门大学学报（自然科学版）2016，Vol.55Issue(6)：802-809,8.DOI:10.6043/j.issn.0438-0479.201603035
新型八元噻吩-乙炔-乙烯环状共轭低聚物的合成及其超分子行为
Synthesis and Supramolecular Performance of a New Type of Eight-membered Thiophene-acetylene-ethylene Cyclic Conj ugated Oligomer
摘要
Abstract
In recent years,Masahiko Iyoda reported a series of macrocyclic compounds composed of thiophene,acetylene,and ethylene building blocks.These macrocyclic compounds own unusualπconj ugated systems and inner cavity structure,which bring a-bout some unique photoelectric performances,such as the two-photon properties and nonlinear optical responses.Here we synthesized a new cyclo[8]thiophene-acetylene-ethylene compound by introducing bithiophene groups.As shown in the crystal structure,uncom-mon S-πweak interactions play key roles during the crystal growth of thiophene rings,intramolecular and intermolecular channel are formed as the result of molecular cavity and perfect crystal packing.Scanning electron microscope(SEM)data show that the macrocy-clic compound forms several centimeters long acicular fiber cluster by self-assembling.Furthermore,fluorescence emission spectrum shows that fluorescence intensities of macrocyclic compound dramatically quench with an increase of the fullerene (C60 ),which con-firms the supramolecular and electronic transfer performance between the electron donor of the macrocyclic compound and the elec-tron acceptor of the fullerene molecule.关键词
噻吩-乙炔-乙烯环状共轭低聚物/S-π相互作用/自组装/富勒烯/超分子行为Key words
thiophene-acetylene-ethylene cyclic conj ugated oligomer/S-π interactions/self-assembling/fullerenes/supramolecular performance分类
化学化工引用本文复制引用
王小祥,张雪鹏,魏诗瑶,徐云彦,张前炎,谢素原,黄荣彬,郑兰荪..新型八元噻吩-乙炔-乙烯环状共轭低聚物的合成及其超分子行为[J].厦门大学学报（自然科学版）,2016,55(6):802-809,8.基金项目
国家自然科学基金(U1205111,21390390,21301143,51572231) （U1205111,21390390,21301143,51572231）
中央高校基本科研业务费专项(20720140512,20720160084,2013121014) （20720140512,20720160084,2013121014）
高等学校博士学科点专项科研基金(20130121120001) （20130121120001）
