印染助剂Issue(11):9-13,5.
聚氧丙烯醚季铵盐表面活性剂在水/异丙醇混合溶剂中胶束行为的研究
Study on micellization behaviors of polypropoxylated cationic surfactants in water/isopropanol solvent mixtures
摘要
Abstract
The micel ization behaviors of polypropoxylated cationic surfactants with the average PO ad⁃duct numbers for four and eight [PO(4)QA, PO(8)QA] in water/isopropanol solvent mixtures were investigated using conductivity and dynamic light scattering (DLS) multi-techniques. The effect of PPO groups on the sur⁃factants micel ization behaviors was also discussed. The results showed that regular or reverse micel occurs with water or alcohol rich solvent mixtures, respectively, and no micel occured in non water or non alcohol sol⁃vent. Electrostatic contribution of PPO groups to the surfactant micel ar properties occurred in the reverse mi⁃cel ization behaviors of surfactants PO(4)QA and PO(8)QA.关键词
聚氧丙烯醚季铵盐表面活性剂/水/异丙醇混合溶剂/胶束行为Key words
polypropoxylated cationic surfactants/water/isopropanol solvent mixtures/micel ization be-haviors分类
化学化工引用本文复制引用
王超,孙永强,智丽飞,张勇,孙晋源,武华萍,MARTINO D S..聚氧丙烯醚季铵盐表面活性剂在水/异丙醇混合溶剂中胶束行为的研究[J].印染助剂,2016,(11):9-13,5.基金项目
国家科技支撑项目(2014BAE03B04);国家国际科技合作专项项目(2013DFA42120);山西省国际科技合作项目 ()