化工进展2016，Vol.35Issue(12)：3942-3953,12.DOI:10.16085/j.issn.1000-6613.2016.12.030
结构可控含氟共聚物的合成及其应用研究新进展
New progress in the synthesis and application of well-defined fluorinated copolymers
摘要
Abstract
In recent years,fluorinated polymers have attracted much attention because of their excellent properties of high resistance to heat and oxygen,superior weatherability,good chemical inertness,low dielectric constants,and low surface energy,and broad application prospect in fields of hydrophobic materials,antifouling materials,surfactant,and contrast agent. Fluorinated copolymers of various topologies have been synthesized and applied in related fields. In this paper,firstly,the properties and current research status of fluorinated polymers are briefly introduced. Secondly,the new research progress of well-defined fluorinated copolymers synthesized by reversible addition-fragmentation chain transfer polymerization(RAFT),atom transfer radical polymerization(ATRP),iodine transfer radical polymerization(ITP),reverse iodine transfer polymerization(RITP),single electron transfer living radical polymerization(SET-LRP),nitroxide-mediated radical polymerization(NMP),and livinganionic polymerization(LAP)are reviewed in detail respectively. In addition,the mechanism, advantage and disadvantage of polymerization,and the properties and applications of the fluorinated copolymer obtained are also summarized. Finally,the research foreground and practical application of the design and synthesis of well-defined fluorinated copolymers based on controlled/“living”polymerization are prospected. We put forward that environmentally friendly functional fluorinated polymers will be the research focuses in the future.关键词
聚合/聚合物/合成/可控/“活性”自由基聚合/含氟(甲基)丙烯酸酯/氟烯烃Key words
polymerization/polymers/synthesis/controlled/“living”radical polymerization/fluoroalkyl(meth)acrylates/fluoroolefin分类
化学化工引用本文复制引用
吕弛,崔崑,岳春波,李树材,马志..结构可控含氟共聚物的合成及其应用研究新进展[J].化工进展,2016,35(12):3942-3953,12.基金项目
上海市自然科学基金项目（14ZR1448700）。 （）
