化工进展2016,Vol.35Issue(12):4001-4006,6.DOI:10.16085/j.issn.1000-6613.2016.12.037
松香基功能性单体的合成及应用
Synthesis and application of rosin-based functional monomer
摘要
Abstract
Rosin is one of the most important forestry resources in China. The main components of rosin include different resin acids. As raw material,it can take part in various reactions to synthesize functional monomers in polymer science field because of its unique chemical structures including double bond and carboxyl group. The rosin can be widely applied in painting,adhesive,aerospace, and other fields. Due to low cost,superior mechanical and thermal properties,as well as environmental friendly and renewable alternative,rosin has drawn wide public attention in polymer science field. This article reviewed the rosin-based functional monomer containing acrylate group,vinyl group,and allyl group,respectively. Its application was mainly discussed in polymer and other new material areas including polyurethane resins,epoxy resins,phenol-formaldehyde resin,organic silicone resin and unsaturated polyester. Based on the rosin-based functional monomers,a series of rosin derivatives as application of new application materials were explored,and provided new perspectives for the novel surfactants,cross-linking agents,shape memory materials and other new fields. Moreover,the prospective direction of rosin-based polymer materials was given.关键词
松香/功能性单体/合成与应用Key words
rosin/functional monomers/synthesis and application分类
化学化工引用本文复制引用
陈莉晶,曹晓琴,徐徐..松香基功能性单体的合成及应用[J].化工进展,2016,35(12):4001-4006,6.基金项目
国家自然科学基金项目(31470597)。 ()