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水热法合成微纳米CuO及在气体传感器中的应用

胡校兵 谢祯芳 谢骥 解丽丽 朱志刚

郑州大学学报(工学版)2016,Vol.37Issue(6):10-14,5.
郑州大学学报(工学版)2016,Vol.37Issue(6):10-14,5.DOI:10.13705/j.issn.1671-6833.2016.03.022

水热法合成微纳米CuO及在气体传感器中的应用

Hydrothermal Synthesis of CuO Micro/Nanoparticles and Their Application in Gas Sensors

胡校兵 1谢祯芳 1谢骥 1解丽丽 1朱志刚1

作者信息

  • 1. 上海第二工业大学 环境与材料工程学院,上海201209
  • 折叠

摘要

Abstract

Micro/Nano-particles of CuO were prepared with hexamethylenetetramine template. The composi-tion and morphology of the product were characterized by SEM and X-ray diffraction. The synthetic powder was prepared as sensitive membrane, and its gas sensitivity was studied with a static gas distribution method. The results indicated that the uniform copper oxide powders was synthesized at the 110℃, and the molar ratio be-tween copper nitrate and hexamethylenetetramine was 1∶45. The spindle structure was around 1~2 μm, and was composed of 100 nm nanoplates. The sensor had better selectivity with CH3 COCH3 and H2 S. Copper ox-ide showed good selectivity to hydrogen sulfide and its sensitivity had a certain degree of improvement after fur-ther doping 0. 25% ~1. 25% noble metal catalyst Pt.

关键词

气体传感器/氧化铜颗粒/水热法/掺杂

Key words

gas sensor/copper oxide particles/hydrothermal method/doping

分类

化学化工

引用本文复制引用

胡校兵,谢祯芳,谢骥,解丽丽,朱志刚..水热法合成微纳米CuO及在气体传感器中的应用[J].郑州大学学报(工学版),2016,37(6):10-14,5.

基金项目

国家自然科学基金资助项目(61471233) (61471233)

上海高校特聘教授(东方学者)计划 (东方学者)

上海市科委基础研究重点项目(13NM1401300) (13NM1401300)

上海市教委曙光计划项目(14SG52) (14SG52)

上海市人才基金资助项目(201346) (201346)

郑州大学学报(工学版)

OA北大核心CSTPCD

1671-6833

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