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制备工艺对蔗糖基碳分子筛结构的影响

张云 傅吉全

化工进展2016,Vol.35Issue(z2):232-237,6.
化工进展2016,Vol.35Issue(z2):232-237,6.DOI:10.16085/j.issn.1000-6613.2016.s2.039

制备工艺对蔗糖基碳分子筛结构的影响

Influence of fabrication processing on sucrose-based carbon molecular sieve

张云 1傅吉全1

作者信息

  • 1. 北京服装学院材料科学与工程学院,北京 100029
  • 折叠

摘要

Abstract

The carbon precursor of sucrose was prepared by K2 CO3 activation synthesis method in which used sucrose as carbon source,F127 as surfactant,carbon molecular sieve obtained by carbonization under nitrogen protection.The samples were characterized by SEM,FTIR and N2-adsorption desorption to optimize the sample preparation process.The results showed that the obtained samples that was the remarkable surface pore structure and the pore developed was composed of a high specific surface area of 1366.4423m2/g,Aperture concentration in 0.64nm a single point of pore volume of 0.865796cm3/g under the condition of carbonization temperature 800℃,K2 CO3 concentration of 0.5mol/L,weight ratio of F127 to starch of 1∶3,reation temperature of 45℃,reaction time of 12h.

关键词

蔗糖/碳酸钾/化学活化/碳分子筛

Key words

sucrose/K2 CO3/chemical activation/carbon molecular sieve

分类

化学化工

引用本文复制引用

张云,傅吉全..制备工艺对蔗糖基碳分子筛结构的影响[J].化工进展,2016,35(z2):232-237,6.

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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