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十四集总催化重整反应动力学模型研究

刘子媛 杜峰 李豪 郭璐玥

中国石油大学学报(自然科学版)2016,Vol.40Issue(6):178-183,6.
中国石油大学学报(自然科学版)2016,Vol.40Issue(6):178-183,6.DOI:10.3969/j.issn.1673-5005.2016.06.023

十四集总催化重整反应动力学模型研究

Research of a 14-lumped kinetic model for catalytic reforming

刘子媛 1杜峰 1李豪 1郭璐玥1

作者信息

  • 1. 中国石油大学化学工程学院,山东青岛266580
  • 折叠

摘要

Abstract

A catalytic reforming kinetic model containing 14 lumped components and twenty-five reactions was proposed, which has a moderate number of lumps and higher prediction accuracy to meet the needs of the production of catalytic refor-ming. On the basis of the experimental data from a micro reactor in the laboratory, the parameters of the catalytic reforming kinetic model were determined. The model was used to predict the composition of the product and to simulate an actual cata-lytic reforming unit. The results show that the maximum absolute deviation is 2. 30%, in which most deviations are less than 2. 0%. The product composition and the temperature distribution in an actual reactor are obtained based on the model, which is in agreement with the catalytic reforming reaction mechanism. The established model has appropriate lumps and can be conveniently used for the prediction of catalytic reforming unit.

关键词

催化重整/动力学/集总/模型

Key words

catalytic reforming/kinetics/lumping/model

分类

能源科技

引用本文复制引用

刘子媛,杜峰,李豪,郭璐玥..十四集总催化重整反应动力学模型研究[J].中国石油大学学报(自然科学版),2016,40(6):178-183,6.

基金项目

中央高校基本科研业务费专项(13CX02056A) (13CX02056A)

中国石油大学学报(自然科学版)

OA北大核心CSCDCSTPCD

1673-5005

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