含能材料2016，Vol.24Issue(12)：1225-1232,8.DOI:10.11943/j.issn.1006-9941.2016.12.017
MOFs作为固体推进剂的燃烧催化剂和含能添加剂的研究进展
Research Progress of MOFs as Combustion Catalysts and High Energy Additives for Solid Propellants
摘要
Abstract
New material is the basis of the development of solid propellant.Among them, the research and development of new energetic materials and combustion catalysts have important significance for improving the properties of solid propellants.Research progresses of metal organic frameworks (MOFs) in heterogeneous catalysis and energetic materials are systematically introduced.It is pointed out that MOFs have higher activity in catalyzing the oxidation reactions of alkanes, alkenes, alcohols and CO, and thus possess ability of catalyzing the propellant combustion reaction.The metal oxides in-situ formed in the combustion process of propellant can also promote the combustion of propellant.MOFs with excellent energy performance and safety performance can be obtained by introducing the high nitrogen content ligands, changing the composition and structure of energetic ligands and their coordination modes with metal ions can effectively tune its energetic performance.Considering that designing and synthesizing the efficient MOFs catalyst used in solid propellant combustion, exploring the reaction mechanism of MOFs in combustion process of propellant, revealing the effect of composition, structure of energetic groups and coordination modes with metal ions on the energetic performance of MOFs may be the research focus in the future.关键词
金属有机框架化合物(MOFs)/固体推进剂/多相催化/燃烧催化剂/含能添加剂Key words
metal organic frameworks (MOFs)/solid propellant/heterogeneous catalysis/burning catalyst/energetic additive分类
军事科技引用本文复制引用
杨燕京,赵凤起,仪建华,轩春雷,罗阳..MOFs作为固体推进剂的燃烧催化剂和含能添加剂的研究进展[J].含能材料,2016,24(12):1225-1232,8.基金项目
国家自然科学基金资助(21173163) （21173163）
