火炸药学报2016，Vol.39Issue(6)：12-19,37,9.DOI:10.14077/j.issn.1007-7812.2016.06.002
α-多硝甲基氧化偶氮含能化合物合成研究进展
Research Progress on the Synthesis of Energetic Compounds Based on α-Polynitromethyl-azoxy Moieties
摘要
Abstract
The construction method of α-polynitromethyl-azoxy moiety was reviewed.The research status on the synthesis of these energetic groups were emphatically introduced using primary amine and 2,2-dimethyl-5-nitro-5-nitroso-1,3-dioxane as raw materials, via oxidative coupling, hydrolysis, dehydroxymethyl and nitration etc.step.The physiochemical properties and detonation performances of 3,3′-bis(dinitromethyl-azoxy)-azoxyfurazan and 3,3′-bis(trinitromethyl-azoxy)azoxyfurazan etc.eight typically reported compounds were analyzed and compared according to the literature and theoretical calculation data.The results show that α-polynitromethyl-azoxy moiety is an ideal structure unit for the synthesis of compounds with high energetic density.Pointed out some novel energetic compounds with excellent performance will be designed and synthesized by the introduction of α-polynitromethyl-azoxy moiety to existing nitrogen heterocycles,with 50 references.关键词
硝甲基氧化偶氮基/含能化合物/高能量密度化合物/伯胺/呋咱类化合物Key words
nitromethyl azoxy moiety/energetic compounds/high energy density compounds/amines/furazan compounds分类
军事科技引用本文复制引用
张家荣,毕福强,王伯周,张俊林,翟连杰,李亚南,贾思媛..α-多硝甲基氧化偶氮含能化合物合成研究进展[J].火炸药学报,2016,39(6):12-19,37,9.基金项目
国家自然科学基金资助项目(No.21503162) （No.21503162）
