火炸药学报2016,Vol.39Issue(6):44-48,5.DOI:10.14077/j.issn.1007-7812.2016.06.007
纳米铝/氧化铜复合材料的制备及热性能
Preparation and Thermal Properties of Nano-Al/CuO Composite
摘要
Abstract
Nano-CuO was prepared using polyethylene glycol (PEG) as template.Nano-Al/CuO composite was prepared by self-assembling using a kind of polymer as coating material.The structure and morphology of the composite were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive spectrometer (EDS), X-ray diffraction (XRD), etc.The thermal properties of samples prepared by self-assembling method (with coating materials) and ultrasonic blending method (without coating materials) were studied and compared by thermogravimetry (TG) and differential scanning calorimetry (DSC).Exothermic quantity of the composite with different Al-CuO molar ratio was investigated.Results show that the exothermic peak occurring the thermite reaction of nano-Al and CuO is at about 576.4℃ and the exothermic quantity is 1093J/g.The composite with coating material has a higher exothermic quantity than that without coating material.The exothermic quantity of the thermite reaction is a maximum, reaching 1093 J/g when the molar ratio of Al and CuO is 1.0∶1.2.关键词
纳米铝热剂/纳米铝/氧化铜/热性能/聚乙二醇/超声共混法Key words
nano thermite/nano-Al/CuO/thermal properties/polyethylene glycol (PEG)/ultrasonic blending method分类
军事科技引用本文复制引用
董小虎,胡岚,汪营磊,舒远杰,严蕊,吴敏杰..纳米铝/氧化铜复合材料的制备及热性能[J].火炸药学报,2016,39(6):44-48,5.基金项目
总装备部高能毁伤科研专项(No.004010201-1) (No.004010201-1)